Engineering Toolbox for Systematic Design of PolyHIPE Architecture.

ABSTRACT: Polymerization of high internal phase emulsions (polyHIPEs) is a well-established method for the production of high porosity foams. Researchers are often regulated to using a time-intensive trial and error approach to achieve target pore architectures. In this work, we performed a systematic study to identify the relative effects of common emulsion parameters on pore architecture (mixing speed, surfactant concentration, organic phase viscosity, molecular hydrophobicity). Across different macromer chemistries, the largest magnitude of change in pore size was observed across surfactant concentration (~6 fold, 5-20 wt%), whereas changing mixing speeds (~4 fold, 500-2000 RPM) displayed a reduced effect. Furthermore, it was observed that organic phase viscosity had a marked effect on pore size

SUBMITTER: Dhavalikar P 

PROVIDER: S-EPMC8124597 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature