Experimental and theoretical study of deep oxidative desulfurization of Dibenzothiophene using Oxalate-Based catalyst.

ABSTRACT: The present study reports the experimental and theoretical investigation for production of ultra-low sulfur liquid fuels through estimation of various reactive species formed during the reaction with the help of simulation. All the experiments were performed using an ultrasound bath which operates at a frequency of 37 kHz and a theoretical power of 95 W. The presented oxalate-based technique is found to be more efficient with > 93% DBT oxidation within 15 min of reaction time at 25 °C due to formation of reactive species like Fe^IIC₂O₄ and [Formula: see text] which accelerate the reaction kinetics. Moreover, we have also investigated the influence of process parameters such as molar ratio of C₂O₄^2-/Fe^{2 +}, oxidant c

SUBMITTER: Chakrabarty S 

PROVIDER: S-EPMC8135043 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature