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CO substitution by PPh₃ in Fe₂S₂(CO)₆ proceeds via a novel Fe₂S intermediate.

ABSTRACT: The reaction of Fe₂S₂(CO)₆ and PPh₃ affords Fe₂S₂(CO)₄(PPh₃)₂ by an unprecedented mechanism involving the intermediacy of SPPh₃ and Fe₂S(CO)₆(PPh₃)₂.

SUBMITTER: Zhang F

PROVIDER: S-EPMC8141036 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature

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CO substitution by PPh₃ in Fe₂S₂(CO)₆ proceeds via a novel Fe₂S intermediate.

OmicsDI is part of the ELIXIR infrastructure

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Dataset Information

CO substitution by PPh3 in Fe2S2(CO)6 proceeds via a novel Fe2S intermediate.

OmicsDI is part of the ELIXIR infrastructure

Tweets

CO substitution by PPh₃ in Fe₂S₂(CO)₆ proceeds via a novel Fe₂S intermediate.