CO substitution by PPh3 in Fe2S2(CO)6 proceeds via a novel Fe2S intermediate.
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ABSTRACT:
SUBMITTER: Zhang F
PROVIDER: S-EPMC8141036 | biostudies-literature | 2021 May
REPOSITORIES: biostudies-literature
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CO substitution by PPh<sub>3</sub> in Fe<sub>2</sub>S<sub>2</sub>(CO)<sub>6</sub> proceeds via a novel Fe<sub>2</sub>S intermediate.
Zhang Fanjun F Woods Toby J TJ Rauchfuss Thomas B TB Arrigoni Federica F Zampella Giuseppe G
Chemical communications (Cambridge, England) 20210423 41
The reaction of Fe<sub>2</sub>S<sub>2</sub>(CO)<sub>6</sub> and PPh<sub>3</sub> affords Fe<sub>2</sub>S<sub>2</sub>(CO)<sub>4</sub>(PPh<sub>3</sub>)<sub>2</sub> by an unprecedented mechanism involving the intermediacy of SPPh<sub>3</sub> and Fe<sub>2</sub>S(CO)<sub>6</sub>(PPh<sub>3</sub>)<sub>2</sub>. ...[more]
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