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Structural and Electrochemical Analysis of CIGS: Cr Crystalline Nanopowders and Thin Films Deposited onto ITO Substrates.


ABSTRACT: A new approach for the synthesis of nanopowders and thin films of CuInGaSe2 (CIGS) chalcopyrite material doped with different amounts of Cr is presented. The chalcopyrite material CuInxGa1 - xSe2 was doped using Cr to form a new doped chalcopyrite with the structure CuInxCryGa1 - x - ySe2, where x = 0.4 and y = 0.0, 0.1, 0.2, or 0.3. The electrical properties of CuInx CryGa1 - x - ySe2 are highly dependent on the Cr content and results show these materials as promising dopants for the fabrication thin film solar cells. The CIGS nano-precursor powder was initially synthesized via an autoclave method, and then converted into thin films over transparent substrates. Both crystalline precursor powders and thin films deposited onto ITO substrates following a spin-coating process were subsequently characterized using XRD, SEM, HR-TEM, UV-visible and electrochemical impedance spectroscopy (EIS). EIS measurement was performed to evaluate the dc-conductivity of these novel materials as conductive films to be applied in solar cells.

SUBMITTER: Saber S 

PROVIDER: S-EPMC8146074 | biostudies-literature | 2021 Apr

REPOSITORIES: biostudies-literature

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Structural and Electrochemical Analysis of CIGS: Cr Crystalline Nanopowders and Thin Films Deposited onto ITO Substrates.

Saber Suzan S   Marí Bernabé B   Andrio Andreu A   Escorihuela Jorge J   Khattab Nagwa N   Eid Ali A   Nahrawy Amany El AE   Abo Aly Mohamed M   Compañ Vicente V  

Nanomaterials (Basel, Switzerland) 20210423 5


A new approach for the synthesis of nanopowders and thin films of CuInGaSe<sub>2</sub> (CIGS) chalcopyrite material doped with different amounts of Cr is presented. The chalcopyrite material CuIn<sub>x</sub>Ga<sub>1 - x</sub>Se<sub>2</sub> was doped using Cr to form a new doped chalcopyrite with the structure CuInxCr<sub>y</sub>Ga<sub>1 - x - y</sub>Se<sub>2</sub>, where x = 0.4 and y = 0.0, 0.1, 0.2, or 0.3. The electrical properties of CuIn<sub>x</sub> Cr<sub>y</sub>Ga<sub>1 - x - y</sub>Se<su  ...[more]

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