Dataset Information

Biomimetic O₂ adsorption in an iron metal-organic framework for air separation.

ABSTRACT: Bio-inspired motifs for gas binding and small molecule activation can be used to design more selective adsorbents for gas separation applications. Here, we report an iron metal-organic framework, Fe-BTTri (Fe₃[(Fe₄Cl)₃(BTTri)₈]₂·18CH₃OH, H₃BTTri = 1,3,5-tris(1H-1,2,3-triazol-5-yl)benzene), that binds O₂ in a manner similar to hemoglobin and therefore results in highly selective O₂ binding. As confirmed by gas adsorption studies and Mössbauer and infrared spectroscopy data, the exposed iron sites in the framework reversibly adsorb substantial amounts of O₂ at low temperatures by converting between high-spin, square-pyramidal Fe(ii) centers in the activated material to low-spin, octahedral Fe(iii)-superoxide sites upon gas binding. This change in both oxidation state and spin state observed in Fe-BTTri leads to selective and readily reversible O₂ binding, with the highest reported O₂/N₂ selectivity for any iron-based framework.

SUBMITTER: Reed DA

PROVIDER: S-EPMC8148054 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Biomimetic O2 adsorption in an iron metal-organic framework for air separation.

Reed Douglas A DA Xiao Dianne J DJ Jiang Henry Z H HZH Chakarawet Khetpakorn K Oktawiec Julia J Long Jeffrey R JR

Chemical science 20200110 6

Bio-inspired motifs for gas binding and small molecule activation can be used to design more selective adsorbents for gas separation applications. Here, we report an iron metal-organic framework, Fe-BTTri (Fe3[(Fe4Cl)3(BTTri)8]2·18CH3OH, H3BTTri = 1,3,5-tris(1H-1,2,3-triazol-5-yl)benzene), that binds O2 in a manner similar to hemoglobin and therefore results in highly selective O2 binding. A ...[more]

PMID: 34084391

Similar Datasets

Project description:Zeolites, silica-supported amines, and metal-organic frameworks (MOFs) have been demonstrated as promising adsorbents for direct air CO2 capture (DAC), but the shaping and structuring of these materials into sorbent modules for practical processes have been inadequately investigated compared to the extensive research on powder materials. Furthermore, there have been relatively few studies reporting the DAC performance of sorbent contactors under cold, subambient conditions (temperatures below 20 °C). In this work, we demonstrate the successful fabrication of adsorbent monoliths composed of cellulose acetate (CA) and adsorbent particles such as zeolite 13X and MOF MIL-101(Cr) by a 3D printing technique: solution-based additive manufacturing (SBAM). These monoliths feature interpenetrated macroporous polymeric frameworks in which microcrystals of zeolite 13X or MIL-101(Cr) are evenly distributed, highlighting the versatility of SBAM in fabricating monoliths containing sorbents with different particle sizes and density. Branched poly(ethylenimine) (PEI) is successfully loaded into the CA/MIL-101(Cr) monoliths to impart CO2 uptakes of 1.05 mmol gmonolith-1 at -20 °C and 400 ppm of CO2. Kinetic analysis shows that the CO2 sorption kinetics of PEI-loaded MIL-101(Cr) sorbents are not compromised in the monoliths compared to the powder sorbents. Importantly, these monoliths exhibit promising working capacities (0.95 mmol gmonolith-1) over 14 temperature swing cycles with a moderate regeneration temperature of 60 °C. Dynamic breakthrough experiments at 25 °C under dry conditions reveal a CO2 uptake capacity of 0.60 mmol gmonolith-1, which further increases to 1.05 and 1.43 mmol gmonolith-1 at -20 °C under dry and humid (70% relative humidity) conditions, respectively. Our work showcases the successful implementation of SBAM in making DAC sorbent monoliths with notable CO2 capture performance over a wide range of sorption temperatures, suggesting that SBAM can enable the preparation of efficient sorbent contactors in various form factors for other important chemical separations.

Dataset Information

Biomimetic O₂ adsorption in an iron metal-organic framework for air separation.

Publications

Biomimetic O<sub>2</sub> adsorption in an iron metal-organic framework for air separation.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets