Zirconium metal-organic frameworks incorporating tetrathiafulvalene linkers: robust and redox-active matrices for in situ confinement of metal nanoparticles.

ABSTRACT: Redox-active metal-organic frameworks (MOFs), with highly ordered porous structures and redox tunability, have attracted research interest in the fields of catalysis, energy storage, and electrochemical sensing. However, the chemical lability has limited the application scope of many redox-active MOFs. Herein, we selected stable Zr₆ inorganic nodes and redox-active tetrathiafulvalene (TTF)-based linkers to construct two robust, redox-active MOFs, namely compounds 1 ([Zr₆(TTFTB)₂O₈(OH₂)₈]) and 2 ([Zr₆(Me-TTFTB)_1.5O₄(OH)₄(C₆H₅COO)₆]) (TTFTB = tetrathiafulvalene tetrabenzoate; Me-TTFTB = tetrathiafulvalene tetramethylbenzoate). The struct

SUBMITTER: Su J 

PROVIDER: S-EPMC8148302 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature