On/off porosity switching and post-assembly modifications of Cu₄L₄ metal-organic polyhedra.

ABSTRACT: Synthetic porous materials composed of metal-organic polyhedra (MOPs) have found application in topical areas such as gas storage, separation and catalysis. Control over their physical properties (e.g. porosity) has typically been achieved through ligand design or judicious choice of metal ions. Here, we demonstrate pore-size control and on/off porosity in Cu₄L₄ MOPs by exploiting their structural non-rigidity. We report an aldehyde-functionalised MOP (1) that can be isolated in five distinct solvatomorphs, each exhibiting different structural flexibility. When soaked in MeOH, two of these solvatomorphs undergo a rapid transformation to a thermodynamically favoured phase, whilst in acetone they template the crystallisation of an entirely new crystal pack

SUBMITTER: Bloch WM 

PROVIDER: S-EPMC8152621 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature