Lanthanide-Aromatic Iminodiacetate Frameworks with Helical Tubes: Structure, Properties, and Low-Temperature Heat Capacity.

ABSTRACT: A series of lanthanide coordination polymers [LnL(H₂O)₂] _n [Ln = Pr (1), Nd (2), Sm (3), Eu (4), and Gd (5), H₃L = N-(4-carboxy-benzyl)iminodiacetic acid] was hydrothermally prepared and structurally characterized. All the five compounds have been confirmed as 3D Ln-CPs with one-dimensional helical tunnels composed of four helical chains, although there are different coordination geometries around Ln³⁺. Enantiomeric helixes in 1-3, and absolute left-handed and right-handed helical chains in 4 and 5, respectively, lead to different tunnel spaces. Their conformations can also be featured by different space groups and unit cell dimensions. Photoluminescence measurement

SUBMITTER: Liu ML 

PROVIDER: S-EPMC8153764 | biostudies-literature | 2021 Apr

REPOSITORIES: biostudies-literature