A New Systematic Construction of Novel Three-Dimensional Spin Crossover Coordination Polymers Based on the [Ag^I ₂(CN)₃] Building Unit.

ABSTRACT: New three-dimensional spin crossover (SCO) coordination polymers systematically constructed by the novel building unit [Ag^I ₂(CN)₃], Fe^II(3-Br-5-CH₃pyridine)₂[Ag^I ₂(CN)₃][Ag^I(CN)₂] (1), Fe^II(3-Br-5-Clpyridine)₂[Ag^I ₂(CN)₃][Ag^I(CN)₂] (2), and Fe^II(3,5-Brpyridine)₂[Ag^I ₂(CN)₃][Ag^I(CN)₂] (3), have been synthesized and characterized. The bismonodentate binuclear [Ag₂(CN)₃]^- and mononuclear [Ag^I(CN)₂]^- units and Fe^II atoms assem

SUBMITTER: Kosone T 

PROVIDER: S-EPMC8154166 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature