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Carbon Dioxide Hydrogenation to Formate Catalyzed by a Bench-Stable, Non-Pincer-Type Mn(I) Alkylcarbonyl Complex.

ABSTRACT: The catalytic reduction of carbon dioxide is a process of growing interest for the use of this simple and abundant molecule as a renewable building block in C1-chemical synthesis and for hydrogen storage. The well-defined, bench-stable alkylcarbonyl Mn(I) bis(phosphine) complex fac-[Mn(CH₂CH₂CH₃)(dippe)(CO)₃] [dippe = 1,2-bis(diisopropylphosphino)ethane] was tested as an efficient and selective non-precious-metal precatalyst for the hydrogenation of CO₂ to formate under mild conditions (75 bar total pressure, 80 °C), in the presence of a Lewis acid co-catalyst (LiOTf) and a base (DBU). Mechanistic insight into the catalytic reaction is provided by means of density functional theory (DFT) calculations.

SUBMITTER: Kostera S

PROVIDER: S-EPMC8155569 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature

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Carbon Dioxide Hydrogenation to Formate Catalyzed by a Bench-Stable, Non-Pincer-Type Mn(I) Alkylcarbonyl Complex.

Kostera Sylwia S Weber Stefan S Peruzzini Maurizio M Veiros Luis F LF Kirchner Karl K Gonsalvi Luca L

Organometallics 20210420 9

The catalytic reduction of carbon dioxide is a process of growing interest for the use of this simple and abundant molecule as a renewable building block in C1-chemical synthesis and for hydrogen storage. The well-defined, bench-stable alkylcarbonyl Mn(I) bis(phosphine) complex fac-[Mn(CH2CH2CH3)(dippe)(CO)3] [dippe = 1,2-bis(diisopropylphosphino)ethane] was tested as an efficient and selective non-precious-metal precatalyst for the hydrogenatio ...[more]

PMID: 34054185

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