Enantioseparation and chiral induction in Ag₂₉ nanoclusters with intrinsic chirality.

ABSTRACT: The optical activity of a metal nanocluster (NC) is induced either by an asymmetric arrangement of constituents or by a dissymmetric field of a chiral ligand layer. Herein, we unveil the origin of chirality in Ag₂₉ NCs, which is attributed to the intrinsically chiral atomic arrangement. The X-ray crystal structure of a Ag₂₉(BDT)₁₂(TPP)₄ NC (BDT: 1,3-benzenedithiol; TPP: triphenylphosphine) manifested the presence of intrinsic chirality in the outer shell capping the icosahedral achiral Ag₁₃ core. The enantiomers of the Ag₂₉(BDT)₁₂(TPP)₄ NC are separated by high-performance liquid chromatography (HPLC) using a chiral column for the first time, showing mirror-image circular dichroism (CD) spectra. The CD

SUBMITTER: Yoshida H 

PROVIDER: S-EPMC8157427 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature