Efficient white polymer light-emitting diodes (WPLEDs) based on covalent-grafting of [Zn2(MP)3(OAc)] into PVK.

ABSTRACT: Thanks to the straightforward white light of single grafting-type polymers based on earth-abundant Zn(ii)-complexes, producing cost-effective flexible WOLEDs/WPLEDs with good device performance remains a formidable challenge. Herein, by using the polymer Poly(NVK-co-[Zn2(MP)3(OAc)]) with excellent physical properties for single-layer WPLEDs, record-high efficiencies (η ^Max _c = 13.0 cd A^-1, η ^Max _p = 6.1 lm W^-1 and η ^Max _EQE = 9.2%) and low (ca. 25%) efficiency roll-off compared to previous organo-Zn²⁺-based WOLEDs/WPLEDs are realized. This finding renders single Zn(ii)-complex-grafted polymers a new route to low-cost and large-area flexible WPLEDs for potent

SUBMITTER: Fu G 

PROVIDER: S-EPMC8157705 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature