B-MWW Zeolite: The Case Against Single-Site Catalysis.

ABSTRACT: Boron-containing materials have recently been identified as highly selective catalysts for the oxidative dehydrogenation (ODH) of alkanes to olefins. It has previously been demonstrated by several spectroscopic characterization techniques that the surface of these boron-containing ODH catalysts oxidize and hydrolyze under reaction conditions, forming an amorphous B₂ (OH)_x O_(3-x/2) (x=0-6) layer. Yet, the precise nature of the active site(s) remains elusive. In this Communication, we provide a detailed characterization of zeolite MCM-22 isomorphously substituted with boron (B-MWW). Using ¹¹ B solid-state NMR spectroscopy, we show that the majority of boron species in B-MWW exist as isolated BO₃ units, fully incorporated into the zeolite

SUBMITTER: Altvater NR 

PROVIDER: S-EPMC8157796 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature