Catalytic C-H Bond Activation and Knoevenagel Condensation Using Pyridine-2,3-Dicarboxylate-Based Metal-Organic Frameworks.

ABSTRACT: Three 1D coordination polymers (CPs) [M(pdca)(H₂O)₂] _n (M = Zn, Cd, and Co; 1-3), and a 3D coordination framework {[(CH₃)₂NH₂][CuK(2,3-pdca)(pa)(NO₃)₂]} _n (4) (2,3-pdca = pyridine-2,3-dicarboxylate and pa = picolinic acid), have been synthesized adopting a solvothermal reaction strategy. The CPs have been thoroughly characterized using various spectral techniques, that is, elemental analyses, FT-IR, TGA, DSC, UV/vis, and luminescence. Structural information on 1-4 was obtained by PXRD and X-ray single-crystal analyses, whereas morphological insights were attained through FESEM, AFM, EDX, HRTEM, and BET surface area analyses. Roughness parameters were calcula

SUBMITTER: Pandey R 

PROVIDER: S-EPMC8158822 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature