An iron ketimide single-molecule magnet [Fe₄(N[double bond, length as m-dash]CPh₂)₆] with suppressed through-barrier relaxation.

ABSTRACT: Reaction of FeBr₂ with 1.5 equiv. of LiN[double bond, length as m-dash]CPh₂ and 2 equiv. of Zn, in THF, results in the formation of the tetrametallic iron ketimide cluster [Fe₄(N[double bond, length as m-dash]CPh₂)₆] (1) in moderate yield. Formally, two Fe centers in 1 are Fe(i) and two are Fe(ii); however, Mössbauer spectroscopy and SQUID magnetometry suggests that the [Fe₄]⁶⁺ core of 1 exhibits complete valence electron delocalization, with a thermally-persistent spin ground state of S = 7. AC and DC SQUID magnetometry reveals the presence of slow magnetic relaxation in 1, indicative of single-molecule magnetic (SMM) behaviour with a relaxation barrier of U _eff

SUBMITTER: Cook AW 

PROVIDER: S-EPMC8159258 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature