Synthetic investigation of competing magnetic interactions in 2D metal-chloranilate radical frameworks.

ABSTRACT: The discovery of emergent materials lies at the intersection of chemistry and condensed matter physics. Synthetic chemistry offers a pathway to create materials with the desired physical and electronic structures that support fundamentally new properties. Metal-organic frameworks are a promising platform for bottom-up chemical design of new materials, owing to their inherent chemical predictability and tunability relative to traditional solid-state materials. Herein, we describe the synthesis and magnetic characterization of a new 2,5-dihydroxy-1,4-benzoquinone based material, (NMe₂H₂)_3.5Ga₂(C₆O₄Cl₂)₃ (1), which features radical-based electronic spins on the sites of a kagomé lattice, a geometric

SUBMITTER: Collins KA 

PROVIDER: S-EPMC8159288 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature