Quantification of the mixed-valence and intervalence charge transfer properties of a cofacial metal-organic framework via single crystal electronic absorption spectroscopy.

ABSTRACT: Gaining a fundamental understanding of charge transfer mechanisms in three-dimensional Metal-Organic Frameworks (MOFs) is crucial to the development of electroactive and conductive porous materials. These materials have potential in applications in porous conductors, electrocatalysts and energy storage devices; however the structure-property relationships pertaining to charge transfer and its quantification are relatively poorly understood. Here, the cofacial Cd(ii)-based MOF [Cd(BPPTzTz)(tdc)]·2DMF (where BPPTzTz = 2,5-bis(4-(pyridin-4-yl)phenyl)thiazolo[5,4-d]thiazole, tdc^2- = 2,5-thiophene dicarboxylate) exhibits Intervalence Charge Transfer (IVCT) within its three-dimensional structure by virtue of the close, cofacial stacking of its redox-active BPPTzTz ligands. The

SUBMITTER: Doheny PW 

PROVIDER: S-EPMC8159307 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature