Synthesis and structures of anionic rhenium polyhydride complexes of boron-hydride ligands and their application in catalysis.

ABSTRACT: The rhenium complex, [K(DME)(18-c-6)][ReH₄(Bpin)(η²-HBpin)(κ²-H₂Bpin)] 1, comprising hydride and boron ligands only, has been synthesized by exhaustive deoxygenation of the commercially available perrhenate anion (ReO₄ ^-) with pinacol borane (HBpin). The structure of 1 was analysed by X-ray crystallography, NMR spectroscopy, and DFT calculations. While no hydrides were located in the X-ray crystal structure, it revealed a trigonal arrangement of pinacol boron ligands. Variable-temperature NMR spectroscopy supported the presence of seven hydride ligands but further insight was hindered by the fluxionality of both hydride and boron ligands at low temperature. Further evaluation of the structure by Ab Initio

SUBMITTER: Donnelly LJ 

PROVIDER: S-EPMC8162066 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature