Palladium-catalyzed hydroalkylation of methylenecyclopropanes with simple hydrazones.

ABSTRACT: A palladium-catalyzed hydroalkylation reaction of methylenecyclopropanes via highly selective C-C σ-bond scission was achieved under mild conditions, in which simple hydrazones served as carbanion equivalents. This method featured good functional group compatibility, affording high yields of C-alkylated terminal alkenes.

SUBMITTER: Yao J 

PROVIDER: S-EPMC8162302 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature