Conservation of structural arrangements and 3 : 1 stoichiometry in a series of crystalline conductors of TMTTF, TMTSF, BEDT-TTF, and chiral DM-EDT-TTF with the oxo-bis[pentafluorotantalate(v)] dianion.

ABSTRACT: The occurrence of isostructural conducting radical cation salts of diversely substituted tetrathiafulvalene (TTF) precursors with the same anion is most often limited to very similar derivatives such as tetramethyl-tetrathiafulvalene (TMTTF) and tetramethyl-tetraselenafulvalene (TMTSF). Here we show that the use of the oxo-bis[pentafluorotantalate(v)] dianion [Ta₂F₁₀O]^2- affords upon electrocrystallization of TMTTF, TMTSF, bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF), racemic dimethyl-ethylenedithio-tetrathiafulvalene ((rac)-DM-EDT-TTF), and enantiopure (S,S)-DM-EDT-TTF a series of mixed valence crystalline radical cation salts with the same 3 : 1 stoichiometry. The donor layers show similar features in the five materials, such as

SUBMITTER: Mroweh N 

PROVIDER: S-EPMC8162395 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature