"Eggs in egg cartons": co-crystallization to embed molecular cages into crystalline lattices.
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ABSTRACT:
SUBMITTER: Domoto Y
PROVIDER: S-EPMC8162400 | biostudies-literature | 2020 Sep
REPOSITORIES: biostudies-literature
Publications
"Eggs in egg cartons": co-crystallization to embed molecular cages into crystalline lattices.
Domoto Yuya Y Abe Masahiro M Yamamoto Kidai K Kikuchi Takashi T Fujita Makoto M
Chemical science 20200915 38
Discrete (M<sub>3</sub>L<sub>2</sub>) <sub><i>n</i></sub> cages assembled from a tripodal ligand (L) and metal ions (M: Cu(i) or Ag(i)) are embedded in networked coordination hosts formed by partial dissociation of the same discrete cages during the crystallization process. The resulting "eggs-in-an-egg-carton" structures provide unique examples of the co-crystallization of discrete and infinite coordination frameworks. ...[more]
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