Multiple rotational rates in a guest-loaded, amphidynamic zirconia metal-organic framework.

ABSTRACT: Amphidynamic motion in metal-organic frameworks (MOFs) is an intriguing emergent property, characterized by high rotational motion of the phenylene rings that are embedded within an open, rigid framework. Here, we show how the phenylene rings in the organic linkers of the water stable MOF PEPEP-PIZOF-2 exhibit multiple rotational rates as a result of the electronic structure of the linker, with and without the presence of highly interacting molecular guests. By selective ²H enrichment, we prepared isotopologues PIZOF-2d4 and PIZOF-2d8 and utilized solid-state ¹³C and ²H NMR to differentiate the dynamic behavior of specific phenylenes in the linker at room temperature. A difference of at least one order of magnitude was observed between

SUBMITTER: Torres-Huerta A 

PROVIDER: S-EPMC8162477 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature