Ontology highlight
ABSTRACT:
SUBMITTER: Meunier A
PROVIDER: S-EPMC8162952 | biostudies-literature | 2020 Oct
REPOSITORIES: biostudies-literature
Meunier Antoine A Singleton Michael L ML Kauffmann Brice B Granier Thierry T Lautrette Guillaume G Ferrand Yann Y Huc Ivan I
Chemical science 20201012 44
As metalloproteins exemplify, the chemical and physical properties of metal centers depend not only on their first but also on their second coordination sphere. Installing arrays of functional groups around the first coordination sphere of synthetic metal complexes is thus highly desirable, but it remains a challenging objective. Here we introduce a novel approach to produce tailored second coordination spheres. We used bioinspired artificial architectures based on aromatic oligoamide foldamers ...[more]