A cyclopentadienyl functionalized silylene - a flexible ligand for Si- and C-coordination.

ABSTRACT: The synthesis of a 1,2,3,4-tetramethylcyclopentadienyl (Cp⁴) substituted four-membered N-heterocyclic silylene [{PhC(NtBu)₂}Si(C₅Me₄H)] is reported first. Then, selected reactions with transition metal and a calcium precursor are shown. The proton of the Cp⁴-unit is labile. This results in two different reaction pathways: (1) deprotonation and (2) rearrangement reactions. Deprotonation was achieved by the reaction of [{PhC(NtBu)₂}Si(C₅Me₄H)] with suitable zinc precursors. Rearrangement to [{PhC(NtBu)₂}(C₅Me₄)SiH], featuring a formally tetravalent silicon R₂C[double bond, length as m-dash]Si(R')-H unit, was observed when the proton of the C

SUBMITTER: Kaufmann S 

PROVIDER: S-EPMC8162997 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature