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Selective synthesis and structural transformation between a molecular ring-in-ring architecture and an abnormal trefoil knot.

ABSTRACT: The synthesis of complicated supramolecular architectures and the study of their reversible structural transformations remains a fascinating challenge in the field of supramolecular chemistry. Herein, two types of novel coordination compounds, a non-intertwined ring-in-ring assembly and an abnormal trefoil knot were constructed from a strategically selected Cp*Rh building block and a semi-rigid N,N'-bis(4-pyridylmethyl)diphthalic diimide ligand via coordination-driven self-assembly. Remarkably, the reversible transformation between the abnormal trefoil knot and the ring-in-ring assembly or the corresponding tetranuclear macrocycle could be achieved by the synergistic effects of Ag⁺ ion coordination and alteration of the solvent. Single-crystal X-ray crystallographic data and NMR spectroscopic experiments support the structural assignments.

SUBMITTER: Dang LL

PROVIDER: S-EPMC8163296 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature

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Selective synthesis and structural transformation between a molecular ring-in-ring architecture and an abnormal trefoil knot.

Dang Li-Long LL Gao Xiang X Lin Yue-Jian YJ Jin Guo-Xin GX

Chemical science 20200715 30

The synthesis of complicated supramolecular architectures and the study of their reversible structural transformations remains a fascinating challenge in the field of supramolecular chemistry. Herein, two types of novel coordination compounds, a non-intertwined ring-in-ring assembly and an abnormal trefoil knot were constructed from a strategically selected Cp*Rh building block and a semi-rigid N,N'-bis(4-pyridylmethyl)diphthalic diimide ligand via coordination-driven self-a ...[more]

PMID: 34094170

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