Driving high quantum yield NIR emission through proquinoidal linkage motifs in conjugated supermolecular arrays.

ABSTRACT: High quantum yield NIR fluorophores are rare. Factors that drive low emission quantum yields at long wavelength include the facts that radiative rate constants increase proportional to the cube of the emission energy, while nonradiative rate constants increase in an approximately exponentially with decreasing S₀-S₁ energy gaps (in accordance with the energy gap law). This work demonstrates how the proquinoidal BTD building blocks can be utilized to minimize the extent of excited-state structural relaxation relative to the ground-state conformation in highly conjugated porphyrin oligomers, and shows that 4-ethynylbenzo[c][1,2,5]thiadiazole (E-BTD) units that terminate meso-to-meso ethyne-bridged (porphinato)zinc (PZnn) arrays, and 4,7

SUBMITTER: Viere EJ 

PROVIDER: S-EPMC8163388 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature