Site-Specific Structure at Multiple Length Scales in Kagome Quantum Spin Liquid Candidates.

ABSTRACT: Realizing a quantum spin liquid (QSL) ground state in a real material is a leading issue in condensed matter physics research. In this pursuit, it is crucial to fully characterize the structure and influence of defects, as these can significantly affect the fragile QSL physics. Here, we perform a variety of cutting-edge synchrotron X-ray scattering and spectroscopy techniques, and we advance new methodologies for site-specific diffraction and L-edge Zn absorption spectroscopy. The experimental results along with our first-principles calculations address outstanding questions about the local and long-range structures of the two leading kagome QSL candidates, Zn-substituted barlowite (Cu₃Zn _x Cu_1-x (OH)₆FBr) and herbertsmithite (Cu

SUBMITTER: Smaha RW 

PROVIDER: S-EPMC8174140 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature