Empowering self-reporting polymer blends with orthogonal optical properties responsive in a broader force range.

ABSTRACT: Self-reporting polymers, which can indicate damage with perceptible optical signals in a tailored force range, are useful as stress-sensitive sensors. We demonstrate a simple approach to realize this function by embedding two distinct mechanophores - rhodamine (Rh) and bis(adamantyl)-1,2-dioxetane (Ad), in polyurethane/polylactic acid blends. The deformed blends generate red coloration and red chemiluminescence. Such a unique dual-responsive behavior was evaluated by solid-state UV-vis spectroscopy, macroscopic tensile tests with in situ RGB and light intensity analyses, which supported a stress-correlated occurrence of the ring-opening of Rh, the scission of Ad and the fluorescence resonance energy transfer process between the respective mechanochemical

SUBMITTER: Wu M 

PROVIDER: S-EPMC8179123 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature