Nucleophilic reactivity of the gold atom in a diarylborylgold(i) complex toward polar multiple bonds.

ABSTRACT: A di(o-tolyl)borylgold complex was synthesized via the metathesis reaction of a gold alkoxide with tetra(o-tolyl)diborane(4). The resulting diarylborylgold complex exhibited a Lewis acidic boron center and a characteristic visible absorption that arises from its HOMO-LUMO excitation, which is narrower than that of a previously reported dioxyborylgold complex. The diarylborylgold complex reacted with isocyanide in a stepwise fashion to afford single- and double-insertion products and a C-C coupled product. Reactions of this diarylborylgold complex with C[double bond, length as m-dash]O/N double bond species furnished addition products under concomitant formation of Au-C and B-O/N bonds, which suggests nucleophilic reactivity of the gold metal center. DFT calculations pr

SUBMITTER: Suzuki A 

PROVIDER: S-EPMC8179162 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature