Reversible carbon-boron bond formation at platinum centers through σ-BH complexes.

ABSTRACT: A reversible carbon-boron bond formation has been observed in the reaction of the coordinatively unsaturated, cyclometalated, Pt(ii) complex [Pt(I ^t BuⁱPr')(I ^t BuⁱPr)][BAr^F], 1, with tricoordinated boranes HBR₂. X-ray diffraction studies provided structural snapshots of the sequence of reactions involved in the process. At low temperature, we observed the initial formation of the unprecedented σ-BH complexes [Pt(HBR₂)(I ^t BuⁱPr')(I ^t BuⁱPr)][BAr^F], one of which has been isolated. From -15 to +10 °C, the σ-BH species undergo a carbon-boron coupling process leading to the platinum hydride derivative [Pt(H)(I ^t

SUBMITTER: Rios P 

PROVIDER: S-EPMC8179255 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature