Defect mitigation using d-penicillamine for efficient methylammonium-free perovskite solar cells with high operational stability.

ABSTRACT: Trap-dominated non-radiative charge recombination is one of the key factors that limit the performance of perovskite solar cells (PSCs), which was widely studied in methylammonium (MA) containing PSCs. However, there is a need to elucidate the defect chemistry of thermally stable, MA-free, cesium/formamidinium (Cs/FA)-based perovskites. Herein, we show that d-penicillamine (PA), an edible antidote for treating heavy metal ions, not only effectively passivates the iodine vacancies (Pb²⁺ defects) through coordination with the -SH and -COOH groups in PA, but also finely tunes the crystallinity of Cs/FA-based perovskite film. Benefiting from these merits, a reduction of non-radiative recombination and an increase in photoluminescence lifetime have been achieved. As a result, the cha

SUBMITTER: Yang J 

PROVIDER: S-EPMC8179333 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature