Distinct electronic structures and bonding interactions in inverse-sandwich samarium and ytterbium biphenyl complexes.

ABSTRACT: Inverse-sandwich samarium and ytterbium biphenyl complexes were synthesized by the reduction of their trivalent halide precursors with potassium graphite in the presence of biphenyl. While the samarium complex had a similar structure as previously reported rare earth metal biphenyl complexes, with the two samarium ions bound to the same phenyl ring, the ytterbium counterpart adopted a different structure, with the two ytterbium ions bound to different phenyl rings. Upon the addition of crown ether to encapsulate the potassium ions, the inverse-sandwich samarium biphenyl structure remained intact; however, the ytterbium biphenyl structure fell apart with the concomitant formation of a divalent ytterbium crown ether complex and potassium biphenylide. Spectroscopic and computational studies w

SUBMITTER: Xiao Y 

PROVIDER: S-EPMC8179684 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature