A new high-voltage calcium intercalation host for ultra-stable and high-power calcium rechargeable batteries.

ABSTRACT: Rechargeable calcium batteries have attracted increasing attention as promising multivalent ion battery systems due to the high abundance of calcium. However, the development has been hampered by the lack of suitable cathodes to accommodate the large and divalent Ca²⁺ ions at a high redox potential with sufficiently fast ionic conduction. Herein, we report a new intercalation host which presents 500 cycles with a capacity retention of 90% and a remarkable power capability at ~3.2 V (vs. Ca/Ca²⁺) in a calcium battery. The cathode material derived from Na_0.5VPO_4.8F_0.7 is demonstrated to reversibly accommodate a large amount of Ca²⁺ ions, forming a series of Ca_xNa_0.5VPO_4.8F_0.7 (0 < x 

SUBMITTER: Xu ZL 

PROVIDER: S-EPMC8184813 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature