Electrochemiluminescence at 3D Printed Titanium Electrodes.

ABSTRACT: The fabrication and electrochemical properties of a 3D printed titanium electrode array are described. The array comprises 25 round cylinders (0.015 cm radius, 0.3 cm high) that are evenly separated on a 0.48 × 0.48 cm square porous base (total geometric area of 1.32 cm²). The electrochemically active surface area consists of fused titanium particles and exhibits a large roughness factor ≈17. In acidic, oxygenated solution, the available potential window is from ~-0.3 to +1.2 V. The voltammetric response of ferrocyanide is quasi-reversible arising from slow heterogeneous electron transfer due to the presence of a native/oxidatively formed oxide. Unlike other metal electrodes, both [Ru(bpy)₃]¹⁺ and [Ru(bpy)₃]³⁺ can be created in aque

SUBMITTER: Douman SF 

PROVIDER: S-EPMC8186460 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature