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An alginate-confined peroxygenase-CLEA for styrene epoxidation.


ABSTRACT: Oxyfunctionalisation reactions in neat substrate still pose a challenge for biocatalysis. Here, we report an alginate-confined peroxygenase-CLEA to catalyse the enantioselective epoxidation of cis-β-methylstyrene in a solvent-free reaction system achieving turnover numbers of 96 000 for the biocatalyst and epoxide concentrations of 48 mM.

SUBMITTER: Nintzel FEH 

PROVIDER: S-EPMC8191455 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature