Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Improving Ammonia Detecting Performance of Polyaniline Decorated rGO Composite Membrane with GO Doping.

ABSTRACT: Gas-sensing performance of graphene-based material has been investigated widely in recent years. Polyaniline (PANI) has been reported as an effective method to improve ammonia gas sensors' response. A gas sensor based on a composite of rGO film and protic acid doped polyaniline (PA-PANI) with GO doping is reported in this work. GO mainly provides NH3 adsorption sites, and PA-PANI is responsible for charge transfer during the gas-sensing response process. The experimental results indicate that the NH3 gas response of rGO is enhanced significantly by decorating with PA-PANI. Moreover, a small amount of GO mixed with PA-PANI is beneficial to increase the gas response, which showed an improvement of 262.5% at 25 ppm comparing to no GO mixing in PA-PANI.

SUBMITTER: Yuan Y

PROVIDER: S-EPMC8198450 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Improving Ammonia Detecting Performance of Polyaniline Decorated rGO Composite Membrane with GO Doping.

Yuan Yubin Y Wu Haiyang H Bu Xiangrui X Wu Qiang Q Wang Xuming X Han Chuanyu C Li Xin X Wang Xiaoli X Liu Weihua W

Materials (Basel, Switzerland) 20210525 11

Gas-sensing performance of graphene-based material has been investigated widely in recent years. Polyaniline (PANI) has been reported as an effective method to improve ammonia gas sensors' response. A gas sensor based on a composite of rGO film and protic acid doped polyaniline (PA-PANI) with GO doping is reported in this work. GO mainly provides NH3 adsorption sites, and PA-PANI is responsible for charge transfer during the gas-sensing response process. The experimental results indic ...[more]

PMID: 34070649

Similar Datasets

MoSe₂-GO/rGO Composite Catalyst for Hydrogen Evolution Reaction.

Project description:There has been considerable research to engineer composites of transition metal dichalcogenides with other materials to improve their catalytic performance. In this work, we present a modified solution-processed method for the formation of molybdenum selenide (MoSe₂) nanosheets and a facile method of structuring composites with graphene oxide (GO) or reduced graphene oxide (rGO) at different ratios to prevent aggregation of the MoSe₂ nanosheets and hence improve their electrocatalytic hydrogen evolution reaction performance. The prepared GO, rGO, and MoSe₂ nanosheets were characterized by X-ray powder diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and scanning electron microscopy. The electrocatalytic performance results showed that the pure MoSe₂ nanosheets exhibited a somewhat high Tafel slope of 80 mV/dec, whereas the MoSe₂-GO and MoSe₂-rGO composites showed lower Tafel slopes of 57 and 67 mV/dec at ratios of 6:4 and 4:6, respectively. We attribute the improved catalytic effects to the better contact and faster carrier transfer between the edge of MoSe₂ and the electrode due to the addition of GO or rGO.

| S-EPMC6401761 | biostudies-literature

Hierarchically Grown NiO-Decorated Polyaniline-Reduced Graphene Oxide Composite for Ultrafast Sunlight-Driven Photocatalysis.

Project description:Polymers and transition-metal oxides have gained great interest as a photocatalyst in environmental remediation. They could be modified with each other in order to improve their activity. Here, a sunlight-responsive hierarchically structured ternary composite of nickel oxide, polyaniline, and reduced graphene oxide (NiO@PANI/RGO) has been synthesized and employed as a catalyst for dye [methylene blue (MB)] degradation. PANI/GO synthesized by interfacial polymerization acts as a matrix for the growth of NiO using a microemulsion solvothermal method, ensuing an in situ reduction of graphene oxide during the formation of a hierarchical NiO@PANI/RGO composite. Morphological studies of the as-synthesized NiO@PANI/RGO composite reveal fine NiO (10 nm) nanoparticles intercalated between the uniformly grown PANI spines (50-60 nm) over the RGO surface. The optical band gap of ∼1.9 eV calculated from the UV-vis spectrum illustrates the extended light absorption range for the NiO@PANI/RGO photocatalyst. The efficiency of 98% MB degradation within 11 min with the degradation rate constant 0.086 min-1 for NiO@PANI/RGO has surpassed any other report on metal oxide/graphene-based ternary composites. Overall, this work could pave the way for the fabrication of futuristic hierarchical structured ternary nanocomposites as an efficient photocatalyst and facilitate their application in the environmental protection issues.

| S-EPMC6644905 | biostudies-literature

MFC reactors with rGO and rGO-Fe composite

Project description:MFC reactors with rGO and rGO-Fe anode modification

| PRJNA978387 | ENA

Chemoresistive Room-Temperature Sensing of Ammonia Using Zeolite Imidazole Framework and Reduced Graphene Oxide (ZIF-67/rGO) Composite.

Project description:The present work demonstrates the application of a composite of the zeolite imidazole framework (ZIF-67) and reduced graphene oxide (rGO), synthesized via a simple hydrothermal route for the sensitive sensing of ammonia. The successful synthesis of ZIF-67 and rGO composite was confirmed with structural and spectroscopic characterizations. A porous structure and a high surface area (1080 m2 g-1) of the composite indicate its suitability as a gas sensing material. The composite material was coated as a thin film onto interdigitated gold electrodes. The sensor displays a change in its chemoresistive property (i.e., resistance) in the presence of ammonia (NH3) gas. A sensor response of 1.22 ± 0.02 [standard deviation (sd)] is measured for 20 ppm of NH3, while it shows a value of 4.77 ± 0.15 (sd) for 50 ppm of NH3. The fabricated sensor is reproducible and offers a stable response, while also providing tolerance against humidity and some other volatile compounds. The average response and recovery times of the sensor, for 50 ppm NH3 concentration, are found to be 46.5 ± 2.12 (sd) and 66.5 ± 2.12 (sd) s, respectively. The limit of detection of the sensor was found to be 74 ppb.

| S-EPMC7594151 | biostudies-literature

A novel CuBi2O4/polyaniline composite as an efficient photocatalyst for ammonia degradation.

Project description:A novel polyaniline (PANI) coupled CuBi2O4 photocatalyst was successfully synthesized via in situ polymerization of aniline with pre-synthesized CuBi2O4 composites. The structure and morphology of the synthesized CuBi2O4/PANI composite photocatalyst were characterized by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) and the photocatalytic performance were evaluated through degradation process of ammonia in water under visible light irradiation. The resultant CuBi2O4/PANI composite showed exceptional stability as its structure and morphology persisted even after being immersed in water for 2 days. The composite photocatalyst exhibited improved charge transport properties due to the electrical conductivity of the PANI protective layer, leading to enhanced photoelectrochemical activity in water and removal of ammonia. PANI with CuBi2O4 (10% wt) heterostructure was applied for photodegradation of ammonia and exhibited a 96% ammonia removal efficiency (30 mg/l with 0.1 g photocatalyst and 180 min), as compared to PANI (78%) and CuBi2O4 (70%). The degradation was attributed to the efficient charge transfer (e- and h+) and formation of reactive oxygen species upon simulated sunlight exposure. The present work suggests that the CuBi2O4/PANI photocatalyst can be synthesized in a simple process and provides an excellent adsorption capacity, high photocatalytic activity, long term stability, and reusability making it a promising alternative for ammonia removal from wastewater.

| S-EPMC9420373 | biostudies-literature

Polyacrylonitrile Nanofiber Membrane Modified with Ag/GO Composite for Water Purification System.

Project description:Silver nanoparticle-modified graphene oxide (Ag/GO) was reliably prepared by using sodium borohydride (NaBH4) in the presence of citric acid capping agent via a simple wet chemistry method. This rapidly formed Ag/GO composite exhibited good dispersity in a solution containing hydrophilic polyacrylonitrile (PAN). Subsequent electrospinning of this precursor solution resulted in the successful formation of nanofibers without any notable defects. The Ag/GO-incorporated PAN nanofibers showed thinner fiber strands (544 ± 82 nm) compared to those of GO-PAN (688 ± 177 nm) and bare-PAN (656 ± 59 nm). Subsequent thermal treatment of nanofibers resulted in the preparation of thin membranes to possess the desired pore property and outstanding wettability. The Ag/GO-PAN nanofiber membrane also showed 30% higher water flux value (390 LMH) than that of bare-PAN (300 LMH) for possible microfiltration (MF) application. In addition, the resulting Ag/GO-PAN nanofiber membrane exhibited antibacterial activity against Escherichia coli (Gram-negative) and Staphylococcus aureus (Gram-positive). Furthermore, this composite membrane exhibited outstanding anti-fouling property compared to the GO-PAN nanofiber membrane in the wastewater treatment. Therefore, the simple modification strategy allows for the effective formation of Ag/GO composite as a filler that can be reliably incorporated into polymer nanofiber membranes to possess improved overall properties for wastewater treatment applications.

| S-EPMC7690632 | biostudies-literature

mRNA microarray analysis on young adults C.elegans exposed to GO and rGO

Project description:In order to evaluate the identification of genes and pathways, the global gene expression profiles were assessed in response to GO and rGO on nematode, Caenorhabditis elegans. We performed whole genome DNA microarray experiments using age synchronized young adult C. elegans population exposed to GO and rGO for 24h. We used whole genome microarrays to screen for global changed in C. elegans transcription profiles and with subsequent quantitative analysis conducted on selected genes.

2016-07-19 | GSE84489 | GEO

Optimized Ammonia-Sensing Electrode with CeO2/rGO Nano-Composite Coating Synthesized by Focused Laser Ablation in Liquid.

Project description:This study investigated the synthesis of cerium oxide (CeO2) nanoparticles (NPs) and composites with reduced graphene oxide (rGO) for the enhanced electrochemical sensing of ammonia. CeO2 NPs were prepared by the focused laser ablation in liquid (LAL) method, which enabled the production of high-purity, spherical nanoparticles with a uniform dispersion and sizes under 50 nm in a short time. The effects of varying irradiation fluence and time on the nanoparticle size, production yield, and dispersion were systematically studied. The synthesized CeO2 NPs were doped with rGO to form CeO2/rGO composites, which were drop casted to modify the glassy carbon electrodes (GCE). The CeO2/rGO-GCE electrodes exhibited superior electrochemical properties compared with single-component electrodes, which demonstrated the significant potential for ammonia detection, especially at a 4 J/cm2 fluence. The CeO2/rGO composites showed uniformly dispersed CeO2 NPs between the rGO sheets, which enhanced the conductivity, as confirmed by SEM, EDS mapping, and XRD analysis. Cyclic voltammetry data demonstrated superior electrochemical activity of the CeO2/rGO composite electrodes, with the 2rGO/1CeO2 ratio showing the highest current response and sensitivity. The CV response to varying ammonia concentrations exhibited a linear relationship, indicating the electrode's capability for accurate quantification. These findings highlight the effectiveness of focused laser ablation in enhancing nanoparticle synthesis and the promising synergistic effects of CeO2 and rGO in developing high-performance electrochemical sensors.

| S-EPMC11314089 | biostudies-literature

Polyaniline Doping by α,α-Difluoro-β-amino Acids.

Project description:Currently, polyaniline (PANI) is considered as a promising polymer that can be used in biosensors, drug delivery systems, bioelectronics, etc. Its biocompatibility can be strongly improved by using dopants with biofunctionality. This study reveals the protonation/doping of PANI by fluorinated analogs of natural amino acids, namely, α,α-difluoro-β-amino acids (DFAAs) with alkyl and aromatic tails in N-methylpyrrolidone solutions. We find that these acids can dope PANI due to both the weakened basicity of their amino groups because of two fluorine atoms in α,α-positions and specific intermolecular interactions (π-π stacking, alkyl-π, F-π) of their tails with units of PANI chains. These interactions did not give the doped PANI salts with high conductivity but led to formation of stable PANI-DFAA complexes, which were confirmed both by clear changes in the UV-Vis and Fourier transform infrared spectra of the protonated/doped PANI and by their conductivity of ∼10-6 S/cm. Our results suggest an applicability of such PANI complexes as carriers of DFAA for their biomedical applications.

| S-EPMC6649075 | biostudies-literature

Synthesis and Characterization of Acetic Acid-Doped Polyaniline and Polyaniline?Chitosan Composite.

Project description:Polyaniline-chitosan (PAni-Cs) composite films were synthesized using a solution casting method with varying PAni concentrations. Polyaniline powders used in the composite synthesis were polymerized using acetic acid as the dopant media. Raman spectroscopy revealed that the PAni powders synthesized using hydrochloric acid and acetic acid did not exhibit significant difference to the chemical features of PAni, implying that PAni was formed in varying concentrations of the dopant media. The presence of agglomerated particles on the surface of the Cs composite, which may have been due to the presence of PAni powders, was observed with scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDX). Ultraviolet-visible (UV-Vis) spectroscopy further showed the interaction of PAni with Cs where the Cs characteristic peak shifted to a higher wavelength. Cell viability assay also revealed that the synthesized PAni-Cs composites were nontoxic and may be utilized for future biomedical applications.

| S-EPMC6477596 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data