Synthesis and Reactivity of Iron Complexes with a Biomimetic SCS Pincer Ligand.

ABSTRACT: Recent experimental evidence suggests that the FeMoco of nitrogenase undergoes structural rearrangement during N₂ reduction, which may result in the generation of coordinatively unsaturated iron sites with two sulfur donors and a carbon donor. In an effort to synthesize and study small-molecule model complexes with a one-carbon/two-sulfur coordination environment, we have designed two new SCS pincer ligands containing a central NHC donor accompanied by thioether- or thiolate-functionalized aryl groups. Metalation of the thioether ligand with Fe(OTf)₂ gives 6-coordinate complexes in which the SCS ligand binds meridionally. In contrast, metalation of the thiolate ligand with Fe(HMDS)₂ gives a four-coordinate pseudotetrahedral amide complex in which the ligand

SUBMITTER: Speelman AL 

PROVIDER: S-EPMC8207233 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature