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Unexpected formation of 1,2- and 1,4-bismethoxyl Sc₃N@I _h-C₈₀ derivatives via regioselective anion addition: an unambiguous structural identification and mechanism study.

ABSTRACT: An attempt to achieve heterocyclic cycloadducts of Sc₃N@I _h-C₈₀ via reaction with Ph₂C[double bond, length as m-dash]O, PhC[triple bond, length as m-dash]CPh or PhC[triple bond, length as m-dash]N in the presence of tetrabutylammonium hydroxide (TBAOH) stored in CH₃OH led to the formation of the unexpected bismethoxyl adducts of Sc₃N@I _h-C₈₀ (1 and 2). Further studies reveal that TBAOH in CH₃OH can boost the CH₃O^- addition efficiently, regardless of the presence of other reagents. Single-crystal X-ray diffraction results firmly assign the molecular structures of 1 and 2 as respective 1,4- and 1,2-bismethoxyl adducts, and r

SUBMITTER: Hu Y

PROVIDER: S-EPMC8208303 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature

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Unexpected formation of 1,2- and 1,4-bismethoxyl Sc₃N@I _h-C₈₀ derivatives via regioselective anion addition: an unambiguous structural identification and mechanism study.

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Unexpected formation of 1,2- and 1,4-bismethoxyl Sc3N@I h-C80 derivatives via regioselective anion addition: an unambiguous structural identification and mechanism study.

OmicsDI is part of the ELIXIR infrastructure

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Unexpected formation of 1,2- and 1,4-bismethoxyl Sc₃N@I _h-C₈₀ derivatives via regioselective anion addition: an unambiguous structural identification and mechanism study.