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Triarylamine-based porous coordination polymers performing both hydrogen atom transfer and photoredox catalysis for regioselective α-amino C(sp³)-H arylation.

ABSTRACT: Direct functionalization of C(sp³)-H bonds in a predictable, selective and recyclable manner has become a central challenge in modern organic chemistry. Through incorporating different triarylamine-containing ligands into one coordination polymer, we present herein a heterogeneous approach to the combination of hydrogen atom transfer (HAT) and photoredox catalysis for regioselective C-H arylation of benzylamines. The different molecular sizes and coordination modes of the ligands, tricarboxytriphenylamine (H₃ TCA) and tris(4-(pyridinyl)phenyl)amine (NPy3), in one coordination polymer consolidate the triarylamine (Ar₃N) moiety into a special structural intermediate, which enhances the chemical and thermal stability of the polymers and diminishe

SUBMITTER: Li H

PROVIDER: S-EPMC8221065 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature

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Triarylamine-based porous coordination polymers performing both hydrogen atom transfer and photoredox catalysis for regioselective α-amino C(sp³)-H arylation.

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Dataset Information

Triarylamine-based porous coordination polymers performing both hydrogen atom transfer and photoredox catalysis for regioselective α-amino C(sp3)-H arylation.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Triarylamine-based porous coordination polymers performing both hydrogen atom transfer and photoredox catalysis for regioselective α-amino C(sp³)-H arylation.