Ontology highlight
ABSTRACT:
SUBMITTER: Wang W
PROVIDER: S-EPMC8222362 | biostudies-literature | 2021 Jun
REPOSITORIES: biostudies-literature
Nature communications 20210623 1
Electrophilic halogenation reactions have been a reliable approach to accessing organohalides. During the past decades, various catalytic systems have been developed for the activation of haleniums. However, there is still a short of effective catalysts, which could cover various halogenation reactions and broad scope of unsaturated compounds. Herein, TEMPO (2,2,6,6-tetramethylpiperidine nitroxide) and its derivatives are disclosed as active catalysts for electrophilic halogenation of olefins, a ...[more]