Synthesis and Crystal Structures of New Strontium Complexes with Aminoalkoxy and β-Diketonato Ligands.

ABSTRACT: New heteroleptic strontium complexes were synthesized using substitution reaction of bis(trimethylsilyl)amide of Sr(btsa)₂·2DME with aminoalkoxide and β-diketonate ligands. The complexes [Sr(bdmp)(btsa)]₂·2THF (1), [Sr(bdeamp)(btsa)]₂ (2), [Sr(dadamb)(btsa)]₂ (3), [Sr(bdmp)(hfac)]₃ (4), [Sr(bdeamp)(hfac)]₃ (5), [Sr(dadamb)(hfac)]₃ (6), and [Sr₃(dadamb)₄(tmhd)₂] (7) were prepared and characterized by means of various analysis techniques such as Fourier transform infrared, NMR, thermogravimetric analysis, and elemental analysis. Complexes 1-3 were further structurally confirmed by single-crystal X-ray crystallography, and they d

SUBMITTER: Park C 

PROVIDER: S-EPMC8223417 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature