Development of microwave assisted-UV digestion using diluted reagents for the determination of total nitrogen in cereals by ion chromatography.

ABSTRACT: The objective of this work is to develop a microwave assisted-ultraviolet (MW-UV) digestion in the presence of dilute HCl and H₂O₂ followed by ion chromatography (IC) measurements for the determination of total nitrogen in cereals. This approach (MW-UV-IC) requires lesser time and does not need environmentally hazardous materials as used in Kjeldhal method. Further, the developed method requires only microliter quantities of dilute HCl and few milliliters of H₂O₂ for the matrix digestion and simultaneous conversion of nitrogen to its ionic species for the subsequent analysis by IC. At the optimized acid concentrations (200 ​μL of 0.1 ​mol ​L^-1 HCl) and microwave power, the nitrogen in the cereals flours is converted to nitrate (NO

SUBMITTER: Rastogi L 

PROVIDER: S-EPMC8239805 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature