Cyanate Formation via Photolytic Splitting of Dinitrogen.

ABSTRACT: Light-driven N₂ cleavage into molecular nitrides is an attractive strategy for synthetic nitrogen fixation. However, suitable platforms are rare. Furthermore, the development of catalytic protocols via this elementary step suffers from poor understanding of N-N photosplitting within dinitrogen complexes, as well as of the thermochemical and kinetic framework for coupled follow-up chemistry. We here present a tungsten pincer platform, which undergoes fully reversible, thermal N₂ splitting and reverse nitride coupling, allowing for experimental derivation of thermodynamic and kinetic parameters of the N-N cleavage step. Selective N-N splitting was also obtained photolytically. DFT computations allocate the productive excitations within the {WNNW} core. Transient absorpt

SUBMITTER: Schluschaß B 

PROVIDER: S-EPMC8243327 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature