Synthesis and Characterization of Symmetrically versus Unsymmetrically Proton-Bridged Hexa-Iron Clusters.

ABSTRACT: Syntheses and magnetic and structural characterization of hexa-iron complexes of derivatized salicylaldoximes are discussed. Complexation of Fe(BF₄)₂·6H₂O with each ligand (H₂ L1 and H₄ L2) in a methanolic-pyridine solution resulted in hexa-iron compounds (C1 and C2, respectively), which each contain two near-parallel metal triangles of [Fe₃-μ₃-O], linked by six fluoride bridges and stabilized by a hydrogen-bonded proton between the μ₃-O groups. Within each metal triangle of C2, Fe(III) ions are connected via the amine "straps" of (H₄ L2-2H). Variable-temperature magnetic susceptibility and Mössbauer data of C1 and C2 indicate the

SUBMITTER: De Silva DNT 

PROVIDER: S-EPMC8246689 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature