Intermolecular Hydroaminoalkylation of Alkynes.

ABSTRACT: Intermolecular hydroaminoalkylation reactions of alkynes with secondary amines, which selectively give access to allylic amines with E configuration of the alkene unit, are achieved in the presence of titanium catalysts. Successful reactions of symmetrically substituted diaryl- and dialkylalkynes as well as a terminal alkyne take place with N-benzylanilines, N-alkylanilines, and N-alkylbenzylamines.

SUBMITTER: Kaper T 

PROVIDER: S-EPMC8248392 | biostudies-literature | 2021 Apr

REPOSITORIES: biostudies-literature