Binding of a TlCl Entity by a Tetragold Tetramercaptothiacalixarene Metalloligand via Metallophilic Interactions.

ABSTRACT: The successive auration of p-tert-butyltetramercaptotetrathiacalix[4]arene, H₄ (MTC[4]), with gold(I) phosphine units was investigated. Through deprotonation with NaOMe, followed by salt metathesis reactions with (PR₃ )AuCl (R=Me, Ph) complexes with two and three [(PR₃ )Au]⁺ moieties could be prepared and isolated, namely [(Ph₃ PAu)₂ H₂ (MTC[4])] and [(Me₃ PAu)₃ H(MTC[4])]. In [(Me₃ PAu)₃ H(MTC[4])] two gold atoms already come close enough to undergo aurophilic interactions. To introduce a fourth [(PR₃ )Au]⁺ entity TlOEt had to be used for the deprotonation, which led to the finding that four gold atoms organised by the (MTC[4])^4- coordin

SUBMITTER: Frank N 

PROVIDER: S-EPMC8251583 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature