Ontology highlight
ABSTRACT:
SUBMITTER: Piesch M
PROVIDER: S-EPMC8251822 | biostudies-literature | 2021 Jun
REPOSITORIES: biostudies-literature
Piesch Martin M Reichl Stephan S Seidl Michael M Balázs Gábor G Scheer Manfred M
Angewandte Chemie (International ed. in English) 20210601 27
A synthetic pathway for the synthesis of novel anionic sandwich complexes with a cyclo-E<sub>3</sub> (E=P, As) ligand as an end deck was developed giving [Cp'''Co(η<sup>3</sup> -E<sub>3</sub> )]<sup>-</sup> (Cp'''=1,2,4-tri-tert-butylcyclopentadienyl, E=P ([5]), As ([6])) in good yields suitable for further reactivity studies. In the reaction with the chlorophosphanes R<sub>2</sub> PCl (R=Ph, Cy, <sup>t</sup> Bu), neutral complexes with a disubstituted cyclo-E<sub>3</sub> P (E=P, As) ligand in [ ...[more]