Persistent peri-Heptacene: Synthesis and In Situ Characterization.

ABSTRACT: n-peri-Acenes (n-PAs) have gained interest as model systems of zigzag-edged graphene nanoribbons for potential applications in nanoelectronics and spintronics. However, the synthesis of n-PAs larger than peri-tetracene remains challenging because of their intrinsic open-shell character and high reactivity. Presented here is the synthesis of a hitherto unknown n-PA, that is, peri-heptacene (7-PA), in which the reactive zigzag edges are kinetically protected with eight 4-tBu-C₆ H₄ groups. The formation of 7-PA is validated by high-resolution mass spectrometry and in situ FT-Raman spectroscopy. 7-PA displays a narrow optical energy gap of 1.01 eV and exhibits persistent stability (t_1/2 ≈25 min) under inert conditions. Moreover, electron-spin resonance measurem

SUBMITTER: Ajayakumar MR 

PROVIDER: S-EPMC8251907 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature