A Novel M₈ L₆ Cubic Cage That Binds Tetrapyridyl Porphyrins: Cage and Solvent Effects in Cobalt-Porphyrin-Catalyzed Cyclopropanation Reactions.

ABSTRACT: Confinement of a catalyst can have a significant impact on catalytic performance and can lead to otherwise difficult to achieve catalyst properties. Herein, we report the design and synthesis of a novel caged catalyst system Co-G@Fe₈ (Zn-L ⋅ 1)₆ , which is soluble in both polar and apolar solvents without the necessity of any post-functionalization. This is a rare example of a metal-coordination cage able to bind catalytically active porphyrins that is soluble in solvents spanning a wide variety of polarity. This system was used to investigate the combined effects of the solvent and the cage on the catalytic performance in the cobalt catalyzed cyclopropanation of styrene, which involves radical intermediates. Kinetic studies show that DMF has a protective influence on

SUBMITTER: Mouarrawis V 

PROVIDER: S-EPMC8252039 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature