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Adducts of the Parent Boraphosphaketene H₂ BPCO and their Decarbonylative Insertion Chemistry.

ABSTRACT: The first examples of Lewis base adducts of the parent boraphosphaketene (H₂ B-PCO) and their cyclodimers are prepared. One of these adducts is shown to undergo mild decarbonylation and phosphinidene insertion into a B-C bond of a borole, forming very rare examples of 1,2-phosphaborinines, B/P isosteres of benzene. The strong donor properties of these 1,2-phosphaborinines are confirmed by the synthesis of their π complexes with the Group 6 metals.

SUBMITTER: Hagspiel S

PROVIDER: S-EPMC8252595 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature

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Adducts of the Parent Boraphosphaketene H₂ BPCO and their Decarbonylative Insertion Chemistry.

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Adducts of the Parent Boraphosphaketene H2 BPCO and their Decarbonylative Insertion Chemistry.

OmicsDI is part of the ELIXIR infrastructure

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Adducts of the Parent Boraphosphaketene H₂ BPCO and their Decarbonylative Insertion Chemistry.